Catálogo de publicaciones - revistas

<jats:p>Using Landau-Ginzburg-Devonshire (LGD) approach, we proposed the analytical description of the influence of chemical strains on spontaneous polarization and the electrocaloric response in ferroelectric core-shell nanorods. We postulate that the nanorod core presents a defect-free single-crystalline ferroelectric material, and elastic defects are accumulated in the ultrathin shell, where they can induce tensile or compressive chemical strains. Finite-element modeling (FEM) based on the LGD approach reveals transitions of domain-structure morphology induced by chemical strains in the <a:math xmlns:a="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"><a:msub><a:mrow><a:mi>Ba</a:mi><a:mi>Ti</a:mi><a:mi mathvariant="normal">O</a:mi></a:mrow><a:mn>3</a:mn></a:msub></a:math> nanorods. Namely, tensile chemical strains induce and support the single-domain state in the central part of the nanorod, while the curled domain structures appear near the unscreened or partially screened ends of the rod. The vortexlike domains propagate toward the central part of the rod and fill it entirely, when the rod is covered by a shell with compressive chemical strains above some critical value. The critical value depends on the nanorod sizes, aspect ratio, and screening conditions at its ends. Both analytical theory and FEM predict that the tensile chemical strains in the shell increase the nanorod polarization, lattice tetragonality, and electrocaloric response well above the values corresponding to the bulk material. The physical reason for the increase is strong electrostriction coupling between the mismatch-type elastic strains induced in the core by chemical strains in the shell. Comparison with earlier XRD data confirmed an increase of the tetragonality ratio in tensile <e:math xmlns:e="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"><e:msub><e:mrow><e:mi>Ba</e:mi><e:mi>Ti</e:mi><e:mi mathvariant="normal">O</e:mi></e:mrow><e:mn>3</e:mn></e:msub></e:math> nanorods compared to the bulk material. Obtained analytical expressions, which are suitable for the description of strain-induced changes in a wide range of multiaxial ferroelectric core-shell nanorods and nanowires, can be useful for strain engineering of advanced ferroelectric nanomaterials for energy storage, harvesting, electrocaloric applications, and negative capacitance elements.</jats:p> <jats:sec> <jats:title/> <jats:supplementary-material> <jats:permissions> <jats:copyright-statement>Published by the American Physical Society</jats:copyright-statement> <jats:copyright-year>2024</jats:copyright-year> </jats:permissions> </jats:supplementary-material> </jats:sec>

<jats:p>The cocktail party effect is the capability to focus one’s auditory attention on particular audio sources while ignoring other audio sources. We propose an experimental strategy to reproduce this ability by designing a time-dependent metasurface composed of independent active mirrors. Each active mirror is a programmable acoustic unit cell capable of hearing, computing, and re-emitting acoustic signals: each of them acts as a convolution filter. The proper configuration of the metasurface temporal filters allows one to establish an acoustic communication link between groups of individuals immersed in the noisy environment: a multiple-user multiple-input, multiple-output acoustic system is built.</jats:p> <jats:sec> <jats:title/> <jats:supplementary-material> <jats:permissions> <jats:copyright-statement>Published by the American Physical Society</jats:copyright-statement> <jats:copyright-year>2024</jats:copyright-year> </jats:permissions> </jats:supplementary-material> </jats:sec>