Catálogo de publicaciones - tesis
Título de Acceso Abierto
Valorización catalítica de aceites vegetales mediante reacciones de metátesis
Pablo Daniel Nieres Apesteguía Carlos Rodolfo Gricelda Alejandra Eimer Gustavo Pablo Romanelli Santiago Eduardo Vaillard Andrés Fernando Trasarti
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Resumen/Descripción – provisto por el repositorio digital
In the present thesis, different routes for the production of valuable chemicals from oleochemical derivatives are postulated. Cross-metathesis of fatty acid esters (FAME) with alkenes is an elegant way to synthesize homologs of these esters and extend extensively the versatility of the metathesis reaction in the field of oleochemistry. In this work, the cross-metathesis of methyl oleate with 3-pentenenitrile, cinnamaldehyde, and ethylene in the liquid phase was studied using the second-generation Hoveyda-Grubbs complex as a catalyst. In addition, the possibility of using a solid catalyst was studied, which was synthesized immobilizing the Hoveyda Grubbs complex in silica.Palabras clave – provistas por el repositorio digital
Olefin Metathesis; Hoveyda Grubbs Complex; Methyl oleate; Cross-metathesis; Ethenolysis; Metátesis de Olefinas; Complejo Hoveyda Grubbs; Oleato de metilo; Metátesis cruzada; Etenólisis
Disponibilidad
| Institución detectada | Año de publicación | Navegá | Descargá | Solicitá |
|---|---|---|---|---|
| No requiere | 2017 | Biblioteca Virtual de la Universidad Nacional del Litoral (SNRD) |
|
Información
Tipo de recurso:
tesis
Idiomas de la publicación
- español castellano
País de edición
Argentina
Fecha de publicación
2017-03-15
