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Institución detectada Período Navegá Descargá Solicitá
No detectada desde mar. 1997 / hasta dic. 2023 Science Journals

Información

Tipo de recurso:

revistas

ISSN impreso

0036-8075

ISSN electrónico

1095-9203

Editor responsable

American Association for the Advancement of Science (AAAS)

País de edición

Estados Unidos

Fecha de publicación

Cobertura temática

Tabla de contenidos

Reducing nonradiative recombination in perovskite solar cells with a porous insulator contact

Wei PengORCID; Kaitian MaoORCID; Fengchun CaiORCID; Hongguang MengORCID; Zhengjie ZhuORCID; Tieqiang LiORCID; Shaojie YuanORCID; Zijian XuORCID; Xingyu FengORCID; Jiahang XuORCID; Michael D. McGeheeORCID; Jixian XuORCID

<jats:p> Inserting an ultrathin low-conductivity interlayer between the absorber and transport layer has emerged as an important strategy for reducing surface recombination in the best perovskite solar cells. However, a challenge with this approach is a trade-off between the open-circuit voltage ( <jats:italic>V</jats:italic> <jats:sub>oc</jats:sub> ) and the fill factor (FF). Here, we overcame this challenge by introducing a thick (about 100 nanometers) insulator layer with random nanoscale openings. We performed drift-diffusion simulations for cells with this porous insulator contact (PIC) and realized it using a solution process by controlling the growth mode of alumina nanoplates. Leveraging a PIC with an approximately 25% reduced contact area, we achieved an efficiency of up to 25.5% (certified steady-state efficiency 24.7%) in p-i-n devices. The product of <jats:italic>V</jats:italic> <jats:sub>oc</jats:sub> × FF was 87.9% of the Shockley-Queisser limit. The surface recombination velocity at the p-type contact was reduced from 64.2 to 9.2 centimeters per second. The bulk recombination lifetime was increased from 1.2 to 6.0 microseconds because of improvements in the perovskite crystallinity. The improved wettability of the perovskite precursor solution allowed us to demonstrate a 23.3% efficient 1-square-centimeter p-i-n cell. We demonstrate here its broad applicability for different p-type contacts and perovskite compositions. </jats:p>

Palabras clave: Multidisciplinary.

Pp. 683-690

Continuous-flow electrosynthesis of ammonia by nitrogen reduction and hydrogen oxidation

Xianbiao FuORCID; Jakob B. PedersenORCID; Yuanyuan ZhouORCID; Mattia SaccoccioORCID; Shaofeng LiORCID; Rokas SažinasORCID; Katja LiORCID; Suzanne Z. AndersenORCID; Aoni XuORCID; Niklas H. DeisslerORCID; Jon Bjarke Valbæk MygindORCID; Chao WeiORCID; Jakob KibsgaardORCID; Peter C. K. VesborgORCID; Jens K. NørskovORCID; Ib ChorkendorffORCID

<jats:p>Ammonia is a critical component in fertilizers, pharmaceuticals, and fine chemicals and is an ideal, carbon-free fuel. Recently, lithium-mediated nitrogen reduction has proven to be a promising route for electrochemical ammonia synthesis at ambient conditions. In this work, we report a continuous-flow electrolyzer equipped with 25–square centimeter–effective area gas diffusion electrodes wherein nitrogen reduction is coupled with hydrogen oxidation. We show that the classical catalyst platinum is not stable for hydrogen oxidation in the organic electrolyte, but a platinum-gold alloy lowers the anode potential and avoids the decremental decomposition of the organic electrolyte. At optimal operating conditions, we achieve, at 1 bar, a faradaic efficiency for ammonia production of up to 61 ± 1% and an energy efficiency of 13 ± 1% at a current density of −6 milliamperes per square centimeter.</jats:p>

Palabras clave: Multidisciplinary.

Pp. 707-712

Ultralow frictional healing explains recurring slow slip events

Srisharan ShreedharanORCID; Demian SafferORCID; Laura M. WallaceORCID; Charles WilliamsORCID

<jats:p>Plate motion on shallow subduction megathrusts is accommodated by a spectrum of tectonic slip modes. However, the frictional properties and conditions that sustain these diverse slip behaviors remain enigmatic. Frictional healing is one such property, which describes the degree of fault restrengthening between earthquakes. We show that the frictional healing rate of materials entrained along the megathrust at the northern Hikurangi margin, which hosts well-characterized recurring shallow slow slip events (SSEs), is nearly zero (&lt;0.0001 per decade). These low healing rates provide a mechanism for the low stress drops (&lt;50 kilopascals) and short recurrence times (1 to 2 years) characteristic of shallow SSEs at Hikurangi and other subduction margins. We suggest that near-zero frictional healing rates, associated with weak phyllosilicates that are common in subduction zones, may promote frequent, small-stress-drop, slow ruptures near the trench.</jats:p>

Palabras clave: Multidisciplinary.

Pp. 712-717

Hard lessons

Jaivime Evaristo

Palabras clave: Multidisciplinary.

Pp. 726-726

The first but not the last

H. Holden Thorp

<jats:p>After 2 years in Washington, DC, Alondra Nelson is returning to Princeton. A highly decorated sociologist who has written and studied extensively on the intersection of genetics and race, she was appointed by President Joe Biden as deputy director for science and society in the Office of Science and Technology Policy (OSTP) in 2021. The following year, when Eric Lander was removed as the head of that office, Nelson stepped in as its interim director until Arati Prabhakar was named permanent director 8 months later. I recently spoke with Nelson, about a range of issues, from scientific publishing to artificial intelligence. She clearly leaves behind a legacy of science policy-making that encourages equity.</jats:p>

Palabras clave: Multidisciplinary.

Pp. 861-861

Ancient DNA upends European prehistory

Andrew Curry

<jats:p>Genes reveal striking diversity within similar ice age cultures</jats:p>

Palabras clave: Multidisciplinary.

Pp. 865-866

Antibody-based defense may protect plants from disease

Erik Stokstad

<jats:p>A “creative” strategy to keep crops healthy borrows key pathogen detectors from the animal immune system</jats:p>

Palabras clave: Multidisciplinary.

Pp. 867-867

Wild mammals add up to a ‘shockingly tiny’ total biomass

Elizabeth Pennisi

<jats:p>Humans and domestic species far outweigh other mammals</jats:p>

Palabras clave: Multidisciplinary.

Pp. 868-868

Wealth gap in biomedical research is growing

Jocelyn Kaiser

<jats:p>Women and Black researchers are less likely to hold multiple NIH grants</jats:p>

Palabras clave: Multidisciplinary.

Pp. 869-869

Do no unconscious harm

Rodrigo Pérez Ortega

<jats:p>Implicit bias can degrade health care. Now, researchers are finding new ways to recognize and mitigate it</jats:p>

Palabras clave: Multidisciplinary.

Pp. 870-873