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<jats:title>Abstract</jats:title><jats:p>While most volcanic arcs show a distinctive spatial relationship to subducting plates, there are many examples where volcanoes occur in anomalous locations. These are commonly also geochemically anomalous relative to the composition of more typical subduction‐related rocks. Using Holocene volcanoes in South America as a case study, we document the spatial and geochemical patterns along the Andean volcanic belt. To determine whether spatial variations are also geochemically anomalous, we assess a series of geochemical indices that provide information on the depth and degree of melting, and the role of metasomatic subduction inputs in melt generation. We use these parameters to develop a scoring system, with the lowest and highest scores indicating “typical” and “anomalous” arc melting processes, respectively. Typical arc magmatism is defined as melts generated in the sub‐arc mantle wedge through slab‐derived fluid metasomatism, with or without contributions from subducted sediments. In contrast, we show that anomalous volcanism in South America appears to relate to geometric anomalies in the subducting Nazca plate (e.g., beneath Sumaco, Laguna Blanca and Payun Matru), or to areas affected by variations in mantle flow due to the proximity to the slab edge (Crater Basalt Volcanic Field). By establishing relationships between anomalous magmatism and slab structure, we propose that similar geochemical fingerprints could be used to explore the magmatic response to slab deformation and/or tearing in older arc systems, particularly in cases where the three‐dimensional slab structure is no longer detectable.</jats:p>