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zirconium-based MOFs; water adsorption; ethanol adsorption; porous materials; adsorption heat pump; coordination polymer; MOF; CP; dimensionality control; Cu(II)-4,4′-bipyridine; dipyridil ligand; copper; metal–organic frameworks; solid sorbents; shaping; gas separation; gas storage; water harvesting; zirconium; metal–organic framework; post-synthetic modification; iridium catalysis; water oxidation; water splitting; thiazole; thiadiazole; coordination polymers; luminescence; cerium; terephthalic acid; spectroscopic characterization; adsorption; calorimetry; carbon dioxide; Ag(I) complexes; metal-organic coordination polymers; thermally activated delayed fluorescence; phosphorescence; pyrimidylphosphines; poly(azolate) spacers; 1,3-bis(1,2,4-triazol-4-yl)adamantane; zinc; cadmium; crystal structure; group 12 metals; 1H-indazole-6-carboxylic acid; photoluminescence properties; organometallic; coordination bonds; supramolecular chemistry; catalysis; n/a