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heterocycle; piperazine; pyrimidine; DABCO; nucleophilic displacement; chlorination; [1,3]-H shift; aza-Michael addition; DFT calculations; dimethyl acetylenedicarboxylate; isoxazolo[3,4-b]quinolin-3(1H)-one; pyrazolines; curcuminoids; nitrogen heterocycles; cytotoxic; DNA binding; MDR reversal; oxygen-nitrogen heterocycles; 11a,12-dihydrobenzo[b]benzo[5,6][1,4]oxazino[2,3-e][1,4]oxazine; disulfur dichloride; o-aminophenol; condensation; 4-anilino-quin(az)olines; hinge binder; conformational flexibility; kinase inhibitor design; imine; Schiff base; X-ray crystallographic analysis; Cu(II) complex; gamma-amino acid; ruthenium; carbonyl complex; azopyridine; anion radical; electronic structure; magnetic properties; chalcogenophene; heterocycles; ligands; pyridine derivatives; thiophene derivatives; aminocyclopentitol; bicyclic aziridine; water chemistry; nucleophilic substitution; homopiperazine; X-ray structure; C–C bond length; 15N-NMR; catechol; alkyne; thiol-alkyne click reaction; domino reactions; bromination; intramolecular SN displacement; carbocyclic hydantoins; N-1 substituted hydantoin; spiro hydantoins; imidazolidine-2,4-diones; stereochemistry; NMR; HRMS; GIAO; ring closing; Au-nanoparticles; NaBH4; amino-substituted fused oxazolocoumarin; fused oxazolocoumarins; chemoselective reduction; o-hydroxynitrocoumarins; benzimidazole; nucleophilic aromatic substitution; thiosemicarbazone; n/a