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<jats:p>Regional heat flow provides a direct surface indication of the thermal state and energy balance of the lithosphere. Heat flux in the Tibetan Plateau remains poorly studied due to the lack of adequate information on heat flow. In this study, we investigated granitoids from the Gonghe-Guide district located in the NE Tibetan Plateau, which have important significance as hot and dry rocks with potential for geothermal resources. Samples from granitoid rocks as well as felsic dikes were collected from this area, and their geochemical data were combined with regional geophysical and drilling core data to evaluate a high-heat-flow anomaly. Our data show that granitoid rocks, including granodiorite, monzogranite, and syenogranite, crystallized at ca. 253−240 Ma, while felsic dikes formed ca. 230 Ma. The former were emplaced during the oceanic subduction process, whereas the latter formed in the syncollisional stage associated with the closure of the paleo-Zongwulong Ocean. Geochemically, these granitoid rocks are metaluminous to slightly peraluminous, with an average differentiation index (DI) value of 80, and they are classified as weakly to moderately fractionated I-type granites. The felsic dikes are peraluminous with high DI values (average of 95), typical of highly fractionated I-type granites. In terms of their high K and especially U and Th abundances, the calculated radioactive heat generation produced by the granodiorite, monzogranite, syenogranite, and felsic dikes is 1.85, 2.91, 6.85, and 3.02 μW/m3, respectively. Their moderate to high heat production generates a local heat-flow anomaly of 14.8−22.2 mW/m2 above the regional value of subduction zones, accounting for 11%−18% of the total regional heat flow. In combination with regional magnetotelluric data, the high-heat-flow anomaly may be attributed to an additional heat-flow contribution from a partial melt layer beneath this region. Furthermore, there is a significant positive correlation between the radioactive heat generation and magmatic fractionation, indicating that the enrichments of heat-producing elements are controlled by fractional crystallization and subsequently source composition. The granitoid rocks with high heat generation correspond to the large-scale intermediate-felsic magmatism during the subduction stage. We propose a model wherein a continuous subduction process during the closure of the paleo-Zongwulong Ocean and protracted cooling and crystallization processes resulted in the enrichment in heat-producing elements.</jats:p>

<jats:p>The East Kunlun orogenic belt in the northern Tibetan Plateau records a long-term accretionary and collisional history in the northeastern Proto-Tethys Ocean, which is important for reconstructing the paleogeography of early Paleozoic East Asia. Here, we present an integrated study combining petrology, geochemistry, geochronology, and metamorphic pressure−temperature (P−T) data of newly found eclogites in the middle Nuomuhong segment of the East Kunlun orogenic belt. The eclogites are composed mainly of garnet, omphacite and low-sodium clinopyroxene, amphibole and plagioclase with minor orthopyroxene, biotite, quartz, accessory rutile, ilmenite, titanite, and zircon. Detailed petrographic observations, conventional geothermobarometry, and phase equilibrium modeling point to the presence of five metamorphic mineral assemblages with corresponding P−T conditions related to: (1) prograde M1 stage P−T estimates at &amp;gt;14.0 kbar/∼470−506 °C; (2) Pmax M2 eclogite-facies stage P−T conditions of ∼26 kbar/∼570 °C; (3) early retrograde M3 high-pressure granulite-facies stage; (4) subsequent M4 retrograde medium-pressure granulite facies at Tmax of ∼860−900 °C; and (5) later M5 retrograde amphibolite-facies stage P−T conditions of &amp;lt;6.2 kbar/∼710−730 °C. These P−T estimates define a clockwise P−T path characterized by heating during the Pmax formation of the eclogite facies, to the Tmax exhumation stage of granulite-facies lithologies, the latter of which is identified for the first time in retrograde eclogites from the East Kunlun orogenic belt. Whole-rock geochemical compositions indicate a mid-oceanic-ridge basalt (MORB) affinity for the eclogite protoliths and a fragmented oceanic crust origin. Sensitive high-resolution ion microprobe (SHRIMP) zircon U−Pb isotopic analyses of the eclogite yielded two groups of weighted mean 206U/238Pb ages of 464 ± 8 Ma and 419 ± 4 Ma, which are interpreted as the age of the eclogite protoliths and the lower threshold for peak eclogite-facies metamorphism, respectively. Our new data, together with regional eclogite-facies metamorphism, suggest a ca. 520−460 Ma age for the subduction of the eastern Kunlun oceanic crust, within the northern Proto-Tethys Ocean, to a depth of ∼83 km, with early subduction−accretionary orogenesis at ca. 419 Ma. Overprinting by high-temperature granulite-facies points to exhumation of oceanic crust to the middle to shallow crustal level at this time. Collectively, the preserved eclogite and high-temperature granulite mineral assemblage provide new constraints on the tectonic evolution and the detailed accretionary-to-collisional orogenesis of the Proto-Tethys Ocean. They suggest that the ca. 428−411 Ma subduction-collisional event marked the termination of the Proto-Tethys Ocean and the eventual formation of an ∼500-km-long, high- to ultra-high−pressure metamorphic belt in the East Kunlun orogenic belt.</jats:p>

<jats:p>The newly identified Neoproterozoic Yuanmou high-Nb mafic and adakitic rocks at the western margin of the Yangtze Block in South China are investigated for petrogenesis and geodynamic implications. Zircon U-Pb ages show the adakitic granodiorite host and mafic microgranular enclaves (MMEs) were synchronously emplaced at 811−806 Ma, and were cut by an 802 ± 11.5 Ma mafic dike. The medium-grained granodiorites consist mainly of plagioclase, quartz, K-felspar, biotite, and amphibole. High SiO2 (62.8−67.5 wt%), Al2O3 (13.1−16.8 wt%) contents, high Sr/Y (17.4−49.0), and (La/Yb)N (16.3−52.6) but low Y (6.83−16.1 ppm) and Yb (0.74−1.82 ppm) concentrations of the granodiorites point toward their calc-alkaline and adakitic nature. Further, their high Dy/Yb (1.52−2.31) and Gd/Y (2.35−4.43) and low K2O/Na2O (0.22−0.48) and Th/La (0.14−0.20) ratios, constant bulk rock εNd(t) (−0.5 to −1.5) and zircon εHf(t) (0.0 to +2.3) values, suggest that the granodiorites were derived from partial melting of a mafic lower crustal source. The MMEs in the granodiorites and mafic dike intrusions are composed of amphibole, plagioclase, clinopyroxene, and olivine, and have similar chemical compositions, such as high Nb (15.7−41.9 ppm) and TiO2 (2.13−3.39 wt%) contents and high Nb/U (18.7−30.9) values, akin to alkaline high-Nb basalts (HNB). Their variable Ba/Nb (7.68−79.2), Nb/Zr (0.09−0.16), high Nb/Th (5.47−6.68), and low Th/Zr (0.01−0.03) and La/Nb (1.03−1.37) ratios indicate a mantle source modified by melts derived from subducted oceanic crust and sediments. The Yuanmou HNB with high εNd(t) (+4.8 to +6.9) were probably generated during back-arc extension by decompression melting of a mantle source metasomatized by adakitic slab melts formed during earlier stages of the subduction. This implies that the location of the back-arc was far from the subducted oceanic slab, possibly due to a slab rollback process. In this scenario, HNB intrusions provided the heat for partial melting and adakitic melt formation in the mafic lower crust. The model suggests that the Yuanmou and other similar associations of HNBs and adakitic rocks emplaced along the western margin of the Yangtze Block are products of a widespread Neoproterozoic back-arc extension.</jats:p>

<jats:p>Nephrite jade is of wide interest, not only for its value as a highly valued precious stone, but also for its significance in tracing geological and petrological processes. Here, we report the first discovery of a nephrite deposit in Africa, located in Somaliland. Field investigations revealed that two open nephrite pits at Goodieood and Laasmacaane are composed of a series of discontinuous vein-shaped nephrite bodies stretching for ∼2 km and defining a nephrite belt. Dolomitic marble and epidote-amphibole are the major rock types in this nephrite belt. Most of the nephrites show grayish green color, while a few are grayish white to light-grayish green, with an occasional brownish rind mainly in nephrite gravels from the secondary deposits. The nephrite is composed of tremolite and actinolite with minor diopside, pargasite, edenite, and apatite. Most nephrites display fine fiber microstructures, and the tremolite-actinolite aggregates show crystallographic preferred orientation. Parallel to the nephrite bodies, epidote-amphibole rocks appear as a metasomatic dark-colored boundary zone, composed mainly of actinolite-tremolite, epidote, and titanite with minor rutile, pargasite, edenite, diopside, and zircon. The dolomitic marble displays dolomite replacement partially by antigorite. Textural observations suggest a sequence from Na-, Al-, and Fe-rich toward Mg-rich compositions, leading to the possibility of prospecting for white nephrite. The various features suggest that the deposit belongs to a fluorine-bearing Ca-Fe-P fluid-dominant skarn. This deposit is estimated to have more than 1000 tons of nephrite jade reserves and has important significance for the exploration for more economic nephrite deposits in Africa, South America, and even Antarctica, as well as potentially important archaeological implications in establishing a connection between the nephrite jades and materials for the Hargeisan lithic industries, as part of the social development in eastern Africa. Comparison with a typical white nephrite deposit in Saidikulam provides insights into the formation of white and nonwhite nephrites.</jats:p>

<jats:p>The Chicxulub impact event at ca. 66 Ma left in its wake the only complex crater on Earth with a preserved peak ring, characterized by a well-developed magnetic anomaly low. To date, little is known about its magnetic properties. The joint Integrated Ocean Drilling Program (IODP) and International Continental Scientific Drilling Program (ICDP) Expedition 364 drill core M0077A revealed that the peak ring consists of uplifted and strongly deformed granitoid basement rocks overlain by a 130-m-thick impact melt and suevite layer. Pre- and postimpact hydrothermal systems affected this basement with maximum temperatures up to 450 °C. We used microscopy, mineral chemistry, temperature-dependent magnetic susceptibility, and hysteresis properties to characterize the magnetic mineralogy of pre-, syn-, and postimpact rocks. Compared to its amount of pure, stoichiometric shocked magnetite, the granitoid basement shows low magnetic susceptibility, which is in line with earlier experimental studies indicating that shock reduces magnetic susceptibility. Cation-substituted magnetite with varying compositions in the melt rocks carries a higher induced and remanent magnetization compared to the basement. In the granitoid basement, magnetite was partially oxidized to hematite by a pre-impact hydrothermal event, but at lithological contacts with high-temperature impact melt rock, this hematite was locally retransformed back to magnetite. Elsewhere in the granitoid basement, the temperature reached in the hydrothermal system was too low for hematite retransformation. It was also too low to anneal all the lattice defects in the shocked magnetite, which likely occurs above 540 °C. The presence of shocked magnetite in the granitoid basement well explains the magnetic anomaly low due to its unusually low induced magnetization.</jats:p>

<jats:p>Most large-scale porphyry-style mineralization is genetically associated with oxidized, sulfur-rich, and hydrous magmas, the sources of which were enriched in mantle-derived or juvenile crust−derived materials. Geochemical indices for these features can distinguish fertile magmas and barren magmas. However, fertile magmas that generate different-sized porphyry deposits are usually geochemically indistinguishable, and the factors controlling the size of porphyry mineralization are poorly understood. Here, we used zircon H2O contents and the compositions of apatite hosted in zircon, phenocrysts, and groundmass to compare the water contents and volatile evolution of fertile magmas in the Yulong ore belt, Tibet, which generated giant-, large-, and medium-sized porphyry deposits. We found that these porphyries have comparable major- and trace-element and zircon Hf-O isotope compositions, with high oxygen fugacity and sulfur contents. A negative correlation between [see PDF for equation] versus [see PDF for equation] of apatites suggests that the magmas consistently achieved H2O saturation before zircon crystallization, and zircon hydroxyl contents reveal that the water contents of the melt positively correlate with the size of the deposits, consistent with larger deposits achieving H2O saturation at deeper crustal levels. The deeper H2O saturation also caused larger amounts of Cl extraction, as indicated by the trends of increasing [see PDF for equation] and decreasing [see PDF for equation] with larger deposit sizes. These data sets can be reconciled by magmas forming larger deposits having higher H2O contents and suggest that the H2O content is a key control on their fertility. Our study highlights the utility of integrated hydrous and nominally anhydrous mineral analyses for constraining enigmatic magmatic volatile processes in magmatic ore-forming systems.</jats:p>

<jats:p>Methane hydrates are widely distributed along continental margins, representing a potential source of methane to the ocean and atmosphere, possibly influencing Earth’s climate. Yet, little is known about the response of methane hydrates to global climate change, especially at the timescale of glacial-interglacial cycles. Here we present a chronology of methane seepage from seep carbonates derived from a series of tens to hundreds of meters long hydrate-bearing sediment records from the South China Sea, drilled at water depths of 664−871 m. We find that six out of seven episodes of intense methane seepage during the last 440,000 years were related to hydrate dissociation, all coinciding with major interglacials, the so-called Marine Isotope Stages 1, 5e, 7c, 9c, and 11c. Using numerical modeling, we show that these events of methane hydrate instability were possibly triggered by the rapid warming of intermediate waters by ∼2.5−3.5 °C in the South China Sea. This finding provides direct evidence for the sensitivity of the deep marine methane hydrate reservoir to glacial-interglacial climatic and oceanographic cyclicity.</jats:p>

<jats:p>The tectonic mechanisms that may trigger a transition from calc-alkaline to alkaline volcanic activity above a subduction zone are enigmatic. We report major/trace elemental and Sr-Nd-Ca isotopic compositions of a suite of magmatic samples from the Miocene Gördes calc-alkaline dacites and the Quaternary Kula alkaline basalts from Western Anatolia, Turkey. Zircon sensitive high-resolution ion microprobe dating shows that the Gördes dacites formed at ca. 18 Ma. They are characterized by high-K calc-alkaline affinities, enrichment of light rare earth elements and large-ion lithophile elements (Rb, Th, U), positive Pb anomalies and negative Eu and high field strength element (HFSE) (Nb, Ta, and Ti) anomalies with high 87Sr/86Sri (0.70977−0.71010) and low εNd(t) (−7.3 to −7.0). They have small δ44/40Ca (0.59‰−0.69‰) values lower than that of mid-ocean ridge basalt (0.83% ± 0.11%). The Kula basalts exhibit alkaline affinities and are more enriched in incompatible elements (e.g., Rb, Ba, Th, Nb, Ta, Pb, and Sr) than those of typical oceanic island basalts. Their low 87Sr/86Sri (0.70307−0.70343) and high εNd(t) (+4.2 to +6.5) are consistent with an asthenospheric mantle source. Their δ44/40Ca values, ranging from 0.67‰ to 0.81‰, are higher than those of the dacites and lower than that of the bulk silicate earth (0.94‰ ± 0.10‰). Geochemical modeling suggests that variable degrees of partial melting of an asthenospheric mantle involving recycled oceanic crust may have resulted in low δ44/40Ca values of the Kula basalts. Combined with reported mantle tomographic images, we interpret that sub-slab asthenospheric mantle upwelling through a slab tear during subduction roll-back may have played a key role in the Sr-Nd-Ca isotopic variability from Miocene calc-alkaline dacites to Quaternary alkaline basalts in Western Anatolia.</jats:p>

<jats:p>We evaluate decadal coarse sediment dynamics along the Marecchia River of the Northern Apennines, a fluvial system with a history of gravel mining that led to the incision of a 6-km-long canyon. To this purpose, we subdivided the river into 21 reaches, seen as sediment reservoirs, to examine (1) historical variations in active channel width (1955−2019) in conjunction with (2) change in alluvial sediment storage (2009−2019), by differencing two sequential LiDAR digital elevation models (DEMs) within the active channel footprint. Combined examination of lateral (widening or narrowing) and vertical (aggradation or degradation) channel changes allowed the identification of composite styles of reservoir adjustment, as well as the refinement of geomorphic inference solely based on changes in active channel width. In particular, we find that different styles of decadal adjustment (1) are compatible with supply- and transport-limited conditions, as constrained by degree of confinement, stream channel slope, and active channel width; and (2) indicate different stages of evolution at reservoirs located upstream and downstream of the canyon head (dynamic equilibrium vs. transient response). The persistence of this geomorphic divide is supported over historical time scales by distinctive trends in planform channel changes, suggesting that sedimentary signal propagation downstream becomes abruptly interrupted at the canyon head. Over this 10-year natural experiment, the spatial pattern of erosion along the canyon exemplifies a striking case of transient response to anthropogenic forcing, where decadal topographic change, modulated by varying styles of hillslope-channel coupling, declines nonlinearly downstream. Depth of incision along the canyon increases progressively upstream, suggesting that the canyon head has been evolving toward a more unstable configuration with no significant change in sediment supply. This tendency, which points to a possible runaway style of development as bedload wearing on weak pelitic side walls continues, may hold basic implications for our understanding of channel incision into bedrock and strath terrace formation.</jats:p>

<jats:p>Understanding of the geodynamic evolution of the Tethyan realm cannot be complete without paleogeographical reconstructions of the North Qiangtang Block (NQB) that occupies a central position in Tibet. However, the reliability of such a reconstruction for the Paleozoic still requires substantial improvement. In this paper, we present paleomagnetic results obtained from the Middle Permian limestones and Upper Permian volcanic rocks in the Tanggula area, aiming to provide precise constraints on the NQB kinematics during the geodynamic evolution of the Tethys realm. Combined with other available paleomagnetic data from the NQB, our results suggest that the block was stably located at ∼24°S for a long time before the Middle Permian, started to drift rapidly northward in the Middle Permian, and reached ∼8.4°S in the Late Permian. The NQB continued drifting rapidly northward during the Triassic until merging with the southern margin of Eurasia in the Late Triassic. We reviewed new and available paleomagnetic and geological data and proposed a revised model for the tectonic evolution of the eastern Tethys realm. The NQB likely belonged to a ribbon-like separate continental archipelago in the middle of the Paleo-Tethys Ocean during the early−late Paleozoic. The Cimmerian continent, including the South Qiangtang Block (SQB), rifted away from the northern margin of Gondwana and drifted northward to ∼22°S in the Middle Permian. The continent approached or partially collided with the NQB, resulting in the rapid northward movement of the NQB and the formation of the Longmuco−Shuanghu suture between the NQB and SQB.</jats:p>