Catálogo de publicaciones - revistas

<jats:p>As hydrogenous iron-manganese crusts grow, at rates of millimeters per million years, they record changes in the lead isotopic composition of ambient seawater. Time-resolved lead isotopic data for cut slabs of two central Pacific iron-manganese crusts that have been growing since about 50 million years ago were measured in situ by laser ablation, multiple-collector, inductively coupled plasma mass spectrometry. The lead isotopic compositions have remained remarkably uniform over the past 30 million years, but the record of small variations corresponds with other paleoceanographic indicators of climate change, including weathering and glaciation. This implies that despite the short residence time of lead in the oceans, global mechanisms may influence lead isotopic compositions in the central Pacific, far from continental inputs, because of changes in weathering, ocean circulation, and degree of mixing. Thus lead isotopic data could be used to probe climate-driven changes in ocean circulation through time.</jats:p>

<jats:p>It is hypothesized that collective efficacy, defined as social cohesion among neighbors combined with their willingness to intervene on behalf of the common good, is linked to reduced violence. This hypothesis was tested on a 1995 survey of 8782 residents of 343 neighborhoods in Chicago, Illinois. Multilevel analyses showed that a measure of collective efficacy yields a high between-neighborhood reliability and is negatively associated with variations in violence, when individual-level characteristics, measurement error, and prior violence are controlled. Associations of concentrated disadvantage and residential instability with violence are largely mediated by collective efficacy.</jats:p>

<jats:p>The oxygen isotopic composition of a banded coral from the western equatorial Indian Ocean provides a 150-year-long history of the relation between the El Niño–Southern Oscillation (ENSO) phenomenon and the Asian monsoon. Interannual cycles in the coral time series were found to correlate with Pacific coral and instrumental climate records, suggesting a consistent linkage across ocean basins, despite the changing frequency and amplitude of the ENSO. However, decadal variability that is characteristic of the monsoon system also dominates the coral record, which implies important interactions between tropical and midlatitude climate variability. One prominent manifestation of this interaction is the strong amplitude modulation of the quasi-biennial cycle.</jats:p>

<jats:p>This paper presents an experimental demonstration of a basic cell of the quantum-dot cellular automata, a transistorless approach to computation that addresses the issues of device density, interconnection, and power dissipation. The device under study was composed of four metal dots, connected with tunnel junctions and capacitors, and operated at &lt;50 mK. Operation was evidenced by switching of a single electron between output dots controlled by a single electron switching in input dots, demonstrating a nonlinear, bistable response.</jats:p>

<jats:p>Although xenon becomes metallic at pressures above about 100 gigapascals, a combination of quantum mechanical calculations and high pressure–temperature experiments reveals no tendency on the part of xenon to form a metal alloy with iron or platinum to at least 100 to 150 gigapascals. The transformation of xenon from face-centered cubic (fcc) to hexagonal close-packed (hcp) structures is kinetically hindered, the differences in volume and bulk modulus between the two phases being smaller than we can resolve (less than 0.3 percent and 0.6 gigapascals, respectively). The equilibrium fcc-hcp phase boundary is at 21 (±3) gigapascals, which is a lower pressure than was previously thought, and it is unlikely that Earth's core serves as a reservoir for primordial xenon.</jats:p>

<jats:p>Argon gas was trapped at high pressure within hollow carbon tubes grown in vapor that have an outer diameter of between 20 and 150 nanometers. The gas was forced into the tubes by hot isostatically pressing (HIPing) the carbon material for 48 hours at 650°C under an argon pressure of 170 megapascals. Energy dispersive x-ray spectroscopy maps and line scans across the tubes show that the argon is trapped inside the bore and not in the tube walls. The room temperature argon pressure in these tubes was estimated to be about 60 megapascals, which indicates that equilibrium pressure was attained within the tubes at the HIPing temperature. These findings demonstrate the potential for storing gases in such carbon structures.</jats:p>

<jats:p>Epoxides are versatile building blocks for organic synthesis. However, terminal epoxides are arguably the most important subclass of these compounds, and no general and practical method exists for their production in enantiomerically pure form. Terminal epoxides are available very inexpensively as racemic mixtures, and kinetic resolution is an attractive strategy for the production of optically active epoxides, given an economical and operationally simple method. Readily accessible synthetic catalysts (chiral cobalt-based salen complexes) have been used for the efficient asymmetric hydrolysis of terminal epoxides. This process uses water as the only reagent, no added solvent, and low loadings of a recyclable catalyst (&lt;0.5 mole percent), and it affords highly valuable terminal epoxides and 1,2-diols in high yield with high enantiomeric enrichment.</jats:p>