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Título de Acceso Abierto
The Astrophysical Journal Supplement (ApJS)
Resumen/Descripción – provisto por la editorial en inglés
The Astrophysical Journal Supplement is an open access journal publishing significant articles containing extensive data or calculations. ApJS also supports Special Issues, collections of thematically related papers published simultaneously in a single volume.Palabras clave – provistas por la editorial
astronomy; astrophysics
Disponibilidad
Institución detectada | Período | Navegá | Descargá | Solicitá |
---|---|---|---|---|
No detectada | desde dic. 1996 / hasta dic. 2023 | IOPScience |
Información
Tipo de recurso:
revistas
ISSN impreso
0067-0049
ISSN electrónico
1538-4365
Editor responsable
American Astronomical Society (AAS)
Idiomas de la publicación
- inglés
País de edición
Reino Unido
Información sobre licencias CC
Cobertura temática
Tabla de contenidos
2021 Census of Interstellar, Circumstellar, Extragalactic, Protoplanetary Disk, and Exoplanetary Molecules
Brett A. McGuire
<jats:title>Abstract</jats:title> <jats:p>To date, 241 individual molecular species, composed of 19 different elements, have been detected in the interstellar and circumstellar medium by astronomical observations. These molecules range in size from two atoms to 70 and have been detected across the electromagnetic spectrum from centimeter wavelengths to the ultraviolet. This census presents a summary of the first detection of each molecular species, including the observational facility, wavelength range, transitions, and enabling laboratory spectroscopic work, as well as listing tentative and disputed detections. Tables of molecules detected in interstellar ices, external galaxies, protoplanetary disks, and exoplanetary atmospheres are provided. A number of visual representations of these aggregate data are presented and briefly discussed in context.</jats:p>
Palabras clave: Space and Planetary Science; Astronomy and Astrophysics.
Pp. 30
A New Catalog of Head–Tail Radio Galaxies from the VLA FIRST Survey
Tapan K. Sasmal; Soumen Bera; Sabyasachi Pal; Soumen Mondal
<jats:title>Abstract</jats:title> <jats:p>The head–tail (HT) morphology of radio galaxies is seen for a class of radio sources where the primary lobes are being bent in the intercluster weather due to strong interactions between the radio jets and their respective intracluster medium. A systematic search has been carried out for new HT radio galaxies from the Very Large Array Faint Images of the Radio Sky at Twenty-Centimeters survey database at 1400 MHz. Here, we present a catalog of 717 new HT sources, among which 287 are narrow-angle tail (NAT) sources whose opening angle between the two lobes is less than 90°, and 430 are wide-angle tail (WAT) whose the opening angle between the two lobes is greater than 90°. NAT radio sources are characterized by tails bent in a narrow “V”-like shape; the jet bending in the case of WAT radio galaxies are such that the WATs exhibit wide “C”-like morphologies. Optical counterparts are found for 359 HT sources. We report HT sources with luminosity ranges 10<jats:sup>38</jats:sup> ≤ <jats:italic>L</jats:italic> <jats:sub>1.4 GHz</jats:sub> ≤ 10<jats:sup>45</jats:sup> erg s<jats:sup>−1</jats:sup> and redshifts up to 2.01. The various physical properties of these HT sources are mentioned here. Some statistical studies have been done for this large number of newly discovered HT sources.</jats:p>
Palabras clave: Space and Planetary Science; Astronomy and Astrophysics.
Pp. 31
Pitfalls of Periodograms: The Nonstationarity Bias in the Analysis of Quasiperiodic Oscillations
Moritz Hübner; Daniela Huppenkothen; Paul D. Lasky; Andrew R. Inglis
<jats:title>Abstract</jats:title> <jats:p>Quasiperiodic oscillations (QPOs) are an important key to understand the dynamic behavior of astrophysical objects during transient events like gamma-ray bursts, solar flares, and magnetar flares. Searches for QPOs often use the periodogram of the time series and perform spectral density estimation using a Whittle likelihood function. However, the Whittle likelihood is only valid if the time series is stationary since the frequency bins are otherwise not statistically independent. We show that if time series are nonstationary, the significance of QPOs can be highly overestimated and estimates of the central frequencies and QPO widths can be overconstrained. The effect occurs if the QPO is only present for a fraction of the time series and the noise level is varying throughout the time series. This can occur, for example, if background noise from before or after the transient is included in the time series or if the low-frequency noise profile varies strongly over the time series. Thus, we highlight the importance of careful segment selection prior to the analysis. We confirm the presence of this bias in previously reported results from solar flare data and show that significance can be highly overstated. Finally, we provide some suggestions that help identify whether an analysis is affected by this bias.</jats:p>
Palabras clave: Space and Planetary Science; Astronomy and Astrophysics.
Pp. 32
The TESS Faint-star Search: 1617 TOIs from the TESS Primary Mission
Michelle Kunimoto; Tansu Daylan; Natalia Guerrero; William Fong; Steve Bryson; George R. Ricker; Michael Fausnaugh; Chelsea X. Huang; Lizhou Sha; Avi Shporer; Andrew Vanderburg; Roland K. Vanderspek; Liang Yu
<jats:title>Abstract</jats:title> <jats:p>We present the detection of 1617 new transiting-planet candidates, identified in the Transiting Exoplanet Survey Satellite (TESS) full-frame images observed during the Primary Mission (Sectors 1–26). These candidates were initially detected by the Quick-Look Pipeline (QLP), which extracts full-frame image lightcurves for, and searches all stars brighter than, TESS magnitude <jats:italic>T</jats:italic> = 13.5 mag in each sector. However, QLP heavily relies on manual inspection for the identification of planet candidates, limiting vetting efforts to planet-hosting stars brighter than <jats:italic>T</jats:italic> = 10.5 mag and leaving millions of potential transit signals unvetted. We describe an independent vetting pipeline applied to QLP transit search results, incorporating both automated vetting tests and manual inspection to identify promising planet candidates around these fainter stars. The new candidates discovered by this ongoing project will allow TESS to significantly improve the statistical power of demographic studies of giant, close-in exoplanets.</jats:p>
Palabras clave: Space and Planetary Science; Astronomy and Astrophysics.
Pp. 33
The Second Catalog of Interplanetary Network Localizations of Konus Short-duration Gamma-Ray Bursts
D. S. Svinkin; K. Hurley; A. V. Ridnaia; A. L. Lysenko; D. D. Frederiks; S. V. Golenetskii; A. E. Tsvetkova; M. V. Ulanov; A. Kokomov; T. L. Cline; I. Mitrofanov; D. Golovin; A. Kozyrev; M. Litvak; A. Sanin; A. Goldstein; M. S. Briggs; C. Wilson-Hodge; E. Burns; A. von Kienlin; X.-L. Zhang; A. Rau; V. Savchenko; E. Bozzo; C. Ferrigno; S. Barthelmy; J. Cummings; H. Krimm; D. M. Palmer; A. Tohuvavohu; K. Yamaoka; M. Ohno; Y. Fukazawa; Y. Hanabata; T. Takahashi; M. Tashiro; Y. Terada; T. Murakami; K. Makishima; W. Boynton; C. W. Fellows; K. P. Harshman; H. Enos; R. Starr; J. Goldsten; R. Gold; A. Ursi; M. Tavani; A. Bulgarelli; C. Casentini; E. Del Monte; Y. Evangelista; M. Galli; F. Longo; M. Marisaldi; N. Parmiggiani; C. Pittori; M. Romani; F. Verrecchia; D. M. Smith; W. Hajdas; S. Xiao; C. Cai; Q. B. Yi; Y. Q. Zhang; S. L. Xiong; X. B. Li; Y. Huang; C. K. Li; S. N. Zhang; L. M. Song; C. Z. Liu; X. Q. Li; W. X. Peng; I. Martinez-Castellanos
<jats:title>Abstract</jats:title> <jats:p>We present the catalog of InterPlanetary Network (IPN) localizations for 199 short-duration gamma-ray bursts (sGRBs) detected by the Konus-Wind (KW) experiment between 2011 January 1 and 2021 August 31, which extends the initial sample of IPN-localized KW sGRBs to 495 events. We present the most comprehensive IPN localization data on these events, including probability sky maps in Hierarchical Equal Area isoLatitude Pixelization format.</jats:p>
Palabras clave: Space and Planetary Science; Astronomy and Astrophysics.
Pp. 34
The Seventeenth Data Release of the Sloan Digital Sky Surveys: Complete Release of MaNGA, MaStar, and APOGEE-2 Data
Abdurro’uf; Katherine Accetta; Conny Aerts; Víctor Silva Aguirre; Romina Ahumada; Nikhil Ajgaonkar; N. Filiz Ak; Shadab Alam; Carlos Allende Prieto; Andrés Almeida; Friedrich Anders; Scott F. Anderson; Brett H. Andrews; Borja Anguiano; Erik Aquino-Ortíz; Alfonso Aragón-Salamanca; Maria Argudo-Fernández; Metin Ata; Marie Aubert; Vladimir Avila-Reese; Carles Badenes; Rodolfo H. Barbá; Kat Barger; Jorge K. Barrera-Ballesteros; Rachael L. Beaton; Timothy C. Beers; Francesco Belfiore; Chad F. Bender; Mariangela Bernardi; Matthew A. Bershady; Florian Beutler; Christian Moni Bidin; Jonathan C. Bird; Dmitry Bizyaev; Guillermo A. Blanc; Michael R. Blanton; Nicholas Fraser Boardman; Adam S. Bolton; Médéric Boquien; Jura Borissova; Jo Bovy; W. N. Brandt; Jordan Brown; Joel R. Brownstein; Marcella Brusa; Johannes Buchner; Kevin Bundy; Joseph N. Burchett; Martin Bureau; Adam Burgasser; Tuesday K. Cabang; Stephanie Campbell; Michele Cappellari; Joleen K. Carlberg; Fábio Carneiro Wanderley; Ricardo Carrera; Jennifer Cash; Yan-Ping Chen; Wei-Huai Chen; Brian Cherinka; Cristina Chiappini; Peter Doohyun Choi; S. Drew Chojnowski; Haeun Chung; Nicolas Clerc; Roger E. Cohen; Julia M. Comerford; Johan Comparat; Luiz da Costa; Kevin Covey; Jeffrey D. Crane; Irene Cruz-Gonzalez; Connor Culhane; Katia Cunha; Y. Sophia Dai; Guillermo Damke; Jeremy Darling; James W. Davidson Jr.; Roger Davies; Kyle Dawson; Nathan De Lee; Aleksandar M. Diamond-Stanic; Mariana Cano-Díaz; Helena Domínguez Sánchez; John Donor; Chris Duckworth; Tom Dwelly; Daniel J. Eisenstein; Yvonne P. Elsworth; Eric Emsellem; Mike Eracleous; Stephanie Escoffier; Xiaohui Fan; Emily Farr; Shuai Feng; José G. Fernández-Trincado; Diane Feuillet; Andreas Filipp; Sean P Fillingham; Peter M. Frinchaboy; Sebastien Fromenteau; Lluís Galbany; Rafael A. García; D. A. García-Hernández; Junqiang Ge; Doug Geisler; Joseph Gelfand; Tobias Géron; Benjamin J. Gibson; Julian Goddy; Diego Godoy-Rivera; Kathleen Grabowski; Paul J. Green; Michael Greener; Catherine J. Grier; Emily Griffith; Hong Guo; Julien Guy; Massinissa Hadjara; Paul Harding; Sten Hasselquist; Christian R. Hayes; Fred Hearty; Jesús Hernández; Lewis Hill; David W. Hogg; Jon A. Holtzman; Danny Horta; Bau-Ching Hsieh; Chin-Hao Hsu; Yun-Hsin Hsu; Daniel Huber; Marc Huertas-Company; Brian Hutchinson; Ho Seong Hwang; Héctor J. Ibarra-Medel; Jacob Ider Chitham; Gabriele S. Ilha; Julie Imig; Will Jaekle; Tharindu Jayasinghe; Xihan Ji; Jennifer A. Johnson; Amy Jones; Henrik Jönsson; Ivan Katkov; Dr. Arman Khalatyan; Karen Kinemuchi; Shobhit Kisku; Johan H. Knapen; Jean-Paul Kneib; Juna A. Kollmeier; Miranda Kong; Marina Kounkel; Kathryn Kreckel; Dhanesh Krishnarao; Ivan Lacerna; Richard R. Lane; Rachel Langgin; Ramon Lavender; David R. Law; Daniel Lazarz; Henry W. Leung; Ho-Hin Leung; Hannah M. Lewis; Cheng Li; Ran Li; Jianhui Lian; Fu-Heng Liang; Lihwai Lin; Yen-Ting Lin; Sicheng Lin; Chris Lintott; Dan Long; Penélope Longa-Peña; Carlos López-Cobá; Shengdong Lu; Britt F. Lundgren; Yuanze Luo; J. Ted Mackereth; Axel de la Macorra; Suvrath Mahadevan; Steven R. Majewski; Arturo Manchado; Travis Mandeville; Claudia Maraston; Berta Margalef-Bentabol; Thomas Masseron; Karen L. Masters; Savita Mathur; Richard M. McDermid; Myles Mckay; Andrea Merloni; Michael Merrifield; Szabolcs Meszaros; Andrea Miglio; Francesco Di Mille; Dante Minniti; Rebecca Minsley; Antonela Monachesi; Jeongin Moon; Benoit Mosser; John Mulchaey; Demitri Muna; Ricardo R. Muñoz; Adam D. Myers; Natalie Myers; Seshadri Nadathur; Preethi Nair; Kirpal Nandra; Justus Neumann; Jeffrey A. Newman; David L. Nidever; Farnik Nikakhtar; Christian Nitschelm; Julia E. O’Connell; Luis Garma-Oehmichen; Gabriel Luan Souza de Oliveira; Richard Olney; Daniel Oravetz; Mario Ortigoza-Urdaneta; Yeisson Osorio; Justin Otter; Zachary J. Pace; Nelson Padilla; Kaike Pan; Hsi-An Pan; Taniya Parikh; James Parker; Sebastien Peirani; Karla Peña Ramírez; Samantha Penny; Will J. Percival; Ismael Perez-Fournon; Marc Pinsonneault; Frédérick Poidevin; Vijith Jacob Poovelil; Adrian M. Price-Whelan; Anna Bárbara de Andrade Queiroz; M. Jordan Raddick; Amy Ray; Sandro Barboza Rembold; Nicole Riddle; Rogemar A. Riffel; Rogério Riffel; Hans-Walter Rix; Annie C. Robin; Aldo Rodríguez-Puebla; Alexandre Roman-Lopes; Carlos Román-Zúñiga; Benjamin Rose; Ashley J. Ross; Graziano Rossi; Kate H. R. Rubin; Mara Salvato; Sebástian F. Sánchez; José R. Sánchez-Gallego; Robyn Sanderson; Felipe Antonio Santana Rojas; Edgar Sarceno; Regina Sarmiento; Conor Sayres; Elizaveta Sazonova; Adam L. Schaefer; Ricardo Schiavon; David J Schlegel; Donald P. Schneider; Mathias Schultheis; Axel Schwope; Aldo Serenelli; Javier Serna; Zhengyi Shao; Griffin Shapiro; Anubhav Sharma; Yue Shen; Matthew Shetrone; Yiping Shu; Joshua D. Simon; M. F. Skrutskie; Rebecca Smethurst; Verne Smith; Jennifer Sobeck; Taylor Spoo; Dani Sprague; David V. Stark; Keivan G. Stassun; Matthias Steinmetz; Dennis Stello; Alexander Stone-Martinez; Thaisa Storchi-Bergmann; Guy S. Stringfellow; Amelia Stutz; Yung-Chau Su; Manuchehr Taghizadeh-Popp; Michael S. Talbot; Jamie Tayar; Eduardo Telles; Johanna Teske; Ani Thakar; Christopher Theissen; Andrew Tkachenko; Daniel Thomas; Rita Tojeiro; Hector Hernandez Toledo; Nicholas W. Troup; Jonathan R. Trump; James Trussler; Jacqueline Turner; Sarah Tuttle; Eduardo Unda-Sanzana; José Antonio Vázquez-Mata; Marica Valentini; Octavio Valenzuela; Jaime Vargas-González; Mariana Vargas-Magaña; Pablo Vera Alfaro; Sandro Villanova; Fiorenzo Vincenzo; David Wake; Jack T. Warfield; Jessica Diane Washington; Benjamin Alan Weaver; Anne-Marie Weijmans; David H. Weinberg; Achim Weiss; Kyle B. Westfall; Vivienne Wild; Matthew C. Wilde; John C. Wilson; Robert F. Wilson; Mikayla Wilson; Julien Wolf; W. M. Wood-Vasey; Renbin Yan; Olga Zamora; Gail Zasowski; Kai Zhang; Cheng Zhao; Zheng Zheng; Zheng Zheng; Kai Zhu
<jats:title>Abstract</jats:title> <jats:p>This paper documents the seventeenth data release (DR17) from the Sloan Digital Sky Surveys; the fifth and final release from the fourth phase (SDSS-IV). DR17 contains the complete release of the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey, which reached its goal of surveying over 10,000 nearby galaxies. The complete release of the MaNGA Stellar Library accompanies this data, providing observations of almost 30,000 stars through the MaNGA instrument during bright time. DR17 also contains the complete release of the Apache Point Observatory Galactic Evolution Experiment 2 survey that publicly releases infrared spectra of over 650,000 stars. The main sample from the Extended Baryon Oscillation Spectroscopic Survey (eBOSS), as well as the subsurvey Time Domain Spectroscopic Survey data were fully released in DR16. New single-fiber optical spectroscopy released in DR17 is from the SPectroscipic IDentification of ERosita Survey subsurvey and the eBOSS-RM program. Along with the primary data sets, DR17 includes 25 new or updated value-added catalogs. This paper concludes the release of SDSS-IV survey data. SDSS continues into its fifth phase with observations already underway for the Milky Way Mapper, Local Volume Mapper, and Black Hole Mapper surveys.</jats:p>
Palabras clave: Space and Planetary Science; Astronomy and Astrophysics.
Pp. 35
A Census of 163 Large-scale (≥10 pc), Velocity-coherent Filaments in the Inner Galactic Plane: Physical Properties, Dense-gas Fraction, and Association with Spiral Arms
Yifei Ge; Ke Wang
<jats:title>Abstract</jats:title> <jats:p>The interstellar medium has a highly filamentary and hierarchical structure that may play a significant role in star formation. A systematical study of the large-scale filaments toward their physical parameters, distribution, structures, and kinematics will inform us about which types of filaments have the potential to form stars, how the material feeds protostars through filaments, and the connection between star formation and Galactic spiral arms. Unlike the traditional by-eye searches, we use a customized minimum spanning tree algorithm to identify filaments by linking Galactic clumps from the APEX Telescope Large Area Survey of the Galaxy catalog. In the inner Galactic plane (∣<jats:italic>l</jats:italic>∣ < 60°), we identify 163 large-scale filaments with physical properties derived, including the dense-gas mass fraction, and we compare them with an updated spiral arm model in position–position–velocity space. The dense-gas mass fraction is found not to differ significantly in various Galactic positions or in different spiral arms. We also find that most filaments are interarm filaments after adding a distance constraint, and filaments in arms differ a little with those not in arms. One surprising result is that clumps on and off filaments have no significant distinction in their mass at the same size.</jats:p>
Palabras clave: Space and Planetary Science; Astronomy and Astrophysics.
Pp. 36
The Infrared Database of Extragalactic Observables from Spitzer. II. The Database and Diagnostic Power of Crystalline Silicate Features in Galaxy Spectra
H. W. W. Spoon; A. Hernán-Caballero; D. Rupke; L. B. F. M. Waters; V. Lebouteiller; A. G. G. M. Tielens; T. Loredo; Y. Su; V. Viola
<jats:title>Abstract</jats:title> <jats:p>We present the Infrared Database of Extragalactic Observables from Spitzer (IDEOS), a homogeneous, publicly available, database of 77 fitted mid-infrared observables in the 5.4–36 <jats:italic>μ</jats:italic>m range, comprising measurements for 3335 galaxies observed in the low-resolution staring mode of the Infrared Spectrometer on board the Spitzer Space Telescope. Among the included observables are polycyclic aromatic hydrocarbon fluxes and their equivalent widths, the strength of the 9.8 <jats:italic>μ</jats:italic>m silicate feature, emission-line fluxes, solid-state features, rest-frame continuum fluxes, synthetic photometry, and a mid-infrared spectral classification. The IDEOS spectra were selected from the Cornell Atlas of Spitzer-IRS Sources. To our surprise, we have detected at a >95% confidence level crystalline silicates in the spectra of 786 IDEOS galaxies. The detections range from single-band detections to detections of all fitted crystalline bands (16, 19, 23, 28, and 33 <jats:italic>μ</jats:italic>m). We find the strength of the crystalline silicate bands to correlate with the amorphous silicate strength and the change from an emission to an absorption feature to occur at higher obscuration as the wavelength of the crystalline silicate band is longer. These observed characteristics are consistent with an origin for the amorphous and crystalline silicate features in a centrally heated dust geometry, either an edge-on disk or a cocoon. We find the 23 and 33 <jats:italic>μ</jats:italic>m crystalline silicate bands to be well suited to classify the obscuration level of galactic nuclei, even in the presence of strong circumnuclear star formation. Based on our detection statistics, we conclude that crystalline silicates are a common component of the interstellar medium of galactic nuclei.</jats:p>
Palabras clave: Space and Planetary Science; Astronomy and Astrophysics.
Pp. 37
A Catalog of Early-type Hα Emission-line Stars and 62 Newly Confirmed Herbig Ae/Be Stars from LAMOST Data Release 7
Yun-Jin Zhang; Wen Hou; A-Li Luo; Shuo Li; Li Qin; Yan Lu; Yin-Bi Li; Jian-Jun Chen; Yong-Heng Zhao
<jats:title>Abstract</jats:title> <jats:p>We derive a catalog of early-type emission-line stars including 30,023 spectra of 25,867 stars from LAMOST Data Release 7, in which 4189 have Simbad records. The spectra are classified into three morphological types (10 subtypes) based on H<jats:italic>α</jats:italic> emission-line profiles. Some spectra contaminated by nebula emission lines such as from H <jats:sc>ii</jats:sc> regions are flagged in the catalog. We also provide a specific catalog of 20 stars with stellar winds or accretion flows by calculating the terminal and peak velocities based on P-Cygni or inverse P-Cygni profiles. More important, with two color–color diagrams, (H-K<jats:sub>s</jats:sub>, J-H) and (K<jats:sub>s</jats:sub>-W1, H-K<jats:sub>s</jats:sub>), of a collection of known Herbig Ae/Be stars (HAeBes) and classical Ae/Be stars (CAeBes), we propose an updated criterion to separate HAeBes from CAeBes. By the criterion, we select 118 HAeBe candidates and 2636 CAeBe candidates from the sample. We confirm 71 of the 118 HAeBes based on the data from LAMOST (optical spectra) and WISE (photometry and images), 62 of which are newly identified. The 71 identified HAeBes are compiled into a specific catalog, and their SEDs and MIR images are also presented. The distances of 76% confirmed HAeBes are further than 1 kpc, which enlarges the number of known HAeBes in further distance. Most of the 71 HAeBes are located in the Galactic disk while 6 of them have ∣<jats:italic>Z</jats:italic> <jats:sub>gal</jats:sub>∣ > 400 pc. Four HAeBes show the forbidden emission lines of [Fe <jats:sc>ii</jats:sc>] and [O <jats:sc>i</jats:sc>], in which J051425.20+411310.7 is a newly discovered B[e]. In addition, four HAeBes having Spitzer IRS spectra all show PAH features.</jats:p>
Palabras clave: Space and Planetary Science; Astronomy and Astrophysics.
Pp. 38
Quantum Mechanical Simulations of the Radical–Radical Chemistry on Icy Surfaces
Joan Enrique-Romero; Albert Rimola; Cecilia Ceccarelli; Piero Ugliengo; Nadia Balucani; Dimitrios Skouteris
<jats:title>Abstract</jats:title> <jats:p>The formation of the interstellar complex organic molecules (iCOMs) is a hot topic in astrochemistry. One of the main paradigms trying to reproduce the observations postulates that iCOMs are formed on the ice mantles covering the interstellar dust grains as a result of radical–radical coupling reactions. We investigate iCOM formation on the icy surfaces by means of computational quantum mechanical methods. In particular, we study the coupling and direct hydrogen abstraction reactions involving the CH<jats:sub>3</jats:sub> + X systems (X = NH<jats:sub>2</jats:sub>, CH<jats:sub>3</jats:sub>, HCO, CH<jats:sub>3</jats:sub>O, CH<jats:sub>2</jats:sub>OH) and HCO + Y (Y = HCO, CH<jats:sub>3</jats:sub>O, CH<jats:sub>2</jats:sub>OH), plus the CH<jats:sub>2</jats:sub>OH + CH<jats:sub>2</jats:sub>OH and CH<jats:sub>3</jats:sub>O + CH<jats:sub>3</jats:sub>O systems. We computed the activation energy barriers of these reactions, as well as the binding energies of all the studied radicals, by means of density functional theory calculations on two ice water models, made of 33 and 18 water molecules. Then, we estimated the efficiency of each reaction using the reaction activation, desorption, and diffusion energies and derived kinetics with the Eyring equations. We find that radical–radical chemistry on surfaces is not as straightforward as usually assumed. In some cases, direct H-abstraction reactions can compete with radical–radical couplings, while in others they may contain large activation energies. Specifically, we found that (i) ethane, methylamine, and ethylene glycol are the only possible products of the relevant radical–radical reactions; (ii) glyoxal, methyl formate, glycolaldehyde, formamide, dimethyl ether, and ethanol formation is likely in competition with the respective H-abstraction products; and (iii) acetaldehyde and dimethyl peroxide do not seem to be likely grain-surface products.</jats:p>
Palabras clave: Space and Planetary Science; Astronomy and Astrophysics.
Pp. 39